Alkenyl succinic anhydride.

Succinic anhydride appears as colorless needles or white crystalline solid. Melting point 237 °F. Sublimes at 239 °F at 5 mmHg pressure; and at 198 °F and 1 mmHg pressure. Moderately toxic and an irritant. CAMEO Chemicals. Succinic anhydride is a cyclic dicarboxylic anhydride and a tetrahydrofurandione.The SUCLG1 gene provides instructions for making one part, the alpha subunit, of an enzyme called succinate-CoA ligase. Learn about this gene and related health conditions. The SUC...In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than …A process for making an alkenyl succinic anhydride having reduced levels of tar and color bodies, said process comprising reacting maleic anhydride with an aliphatic olefin containing about 4-250 carbon atoms at a temperature of about 190°-250° C. in the presence of a triarylphosphite having the structure: ##STR2## wherein R 1 is a tert-alkyl ...@article{Sato2016SurfaceMO, title={Surface modification of cellulose nanofibers with alkenyl succinic anhydride for high-density polyethylene reinforcement}, author={Akihiro Sato and Daisuke Kabusaki and Hiroaki Okumura and Takeshi Nakatani and Fumiaki Nakatsubo and Hiroyuki Yano}, journal={Composites Part A-applied Science and …

Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose. Several experiments were conducted to bring more clarity to the ASA sizing …

Abstract. Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the …Alkenyl succinic anhydride from methyl oleate was isolated by column chromatography and analyzed by IR, 1 H- and 13 C-NMR and MS. The optimal reaction conditions for obtaining the maximum yield of alkenyl succinic anhydride from methyl oleate in the experimental domain (80%) were 210-220 °C and a maleic anhydride/rapeseed oil methyl ester ...

A process for making an alkenyl succinic anhydride having reduced levels of tar and color bodies, said process comprising reacting maleic anhydride with an aliphatic olefin containing about 4-250 carbon atoms at a temperature of about 190°-250° C. in the presence of a triarylphosphite having the structure: ##STR2## wherein R 1 is a tert-alkyl ...Films obtained from pristine tree gums are often brittle, hygroscopic, and lack mechanical strength. This study focuses on the chemical modification of gum kondagogu using long-chain alkenyl groups of dodecenyl succinic anhydride (DDSA), an esterifying agent that introduces a 12-carbon hydrophobic chain to the kondagogu structure. Alkenyl succinic anhydrides (ASA) have been prepared by ene-reaction of high-oleic Agro-Industrielle UMR 1010. INRA/INP-ENSIACET, Toulouse, France sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. Response surface methodology (RSM) was used to investigate the influence of two factors: reaction temperature and molar ratio ... Autism symptoms are actually differences in sensory, communication, and behavior patterns. Here's why. Signs of autism spectrum disorder include differences in communication and be...

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Alkenyl Succinic Anhydride (ASA) is sizing agent that is applied as an aqueous emulsion during the papermaking process to improve paper’s hydrophobicity. However, its application becomes difficult as the emulsion quickly destabilizes due to the coalescence phenomenon and the high reactivity of ASA with water.

Encapsulation of alkenyl succinic anhydride oil droplets in emulsions: Preparation, characterization, stability properties and application in papermaking. …Alkenyl succinic anhydrides ( ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso- alkenyl chain (C 14 to C 22 ). ASA's are colorless and usually viscous liquids. They are widely used, especially in surface sizing of paper, paperboard, and cardboard, as well as in the hydrophobicization of ...“Alkenyl Succinic Anhydride (ASA) Market” Insights Report 2024 | Spread Across 91 Pages Report which provides an in-depth analysis Based on Regions, Applications (Sizing Agent, Curing Agent ...A process for the preparation of an alkenyl-substituted succinic anhydride wherein the alkenyl substituent has a number average molecular weight of from about 500 to 5000 and the average number of succinic groups per alkenyl group is greater than 1.2 which comprises: (a) reacting a polyolefin having an alkylvinylidene isomer content of less than about 10 percent and a number average molecular ...Phthalic anhydride (PA) is a white crystalline compound used to manufacture plasticizers, pigments, dyes and resins. One major consumer of PA is the phthalate plasticiser industry, the products of which are used to produce flexible plastic products such as wire & cable applications, hoses, pipes, coated fabrics, roofing membranes and swimming pool liners.

Jun 29, 2023 · Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose. CELLULOSE STRUCTURE HYDROPHOBIZATION BY ALKENYL SUCCINIC ANHYDRIDE (ASA) – A Novel Approach to Performance Explanation a presentationby S. Porkert, Munich University of Applied Sciences S ...Oct 19, 2021 ... The group can be described as succinic anhydrides with various alkyl chain lengths as result of the reaction of maleic anhydride with ...Alkenyl succinic anhydride (ASA) is one of the most prominent paper sizing agents worldwide. Commercial products start from isomerized C16-18 olefins with certain distribution of the double bond ...A process for the preparation of an alkenyl-substituted succinic anhydride wherein the alkenyl substituent has a number average molecular weight of from about 500 to 5000 and the average number of succinic groups per alkenyl group is greater than 1.2 which comprises: (a) reacting a polyolefin having an alkylvinylidene isomer content of less than about 10 percent and a number average molecular ... Wood flour was also esterified with a commercial alkenyl succinic anhydride (ASA) (Acha et al., 2003; Marcovich et al., 2005, Fig. 4.6). The FTIR spectrum of the treated sample revealed the usual increase in the intensity of the carbonyl absorption at 1735 cm − 1 , owing to ester formation, and the absence of the anhydride absorption bands at ... OxyContin maker Purdue Pharma has a patent for a form of opioid addiction treatment, which means it could profit from combatting the scourge. Richard Sackler, whose family owns Pur...

Octenyl succinic anhydride is an unsaturated cyclic anhydride that undergoes esterification with hydroxyl containing species under basic conditions. Due to the esterification, the addition of hydrophobic carbon chains and hydrophilic carboxylate groups to the fibers simultaneously increases their amphiphilicity (Xiao et al., 2019).

Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsification of ASA using cationic starch is conventionally practiced because of the ...The succinic anhydride reaction with proteins is considered to specifically occur at the free amino groups of proteins, hence replacing the amino group (NH 3 +), at neutral pH with NHCOCH 2 CH 2 COO function [55]. A similar mechanism can be considered for alkenyl-substituted succinic anhydride. Alkenyl succinic anhydrides. These compounds have a wide variety of uses – from manufacturing modified starch, as a hardener for epoxy resin, as anti-corrosive agent, in the production of surfactants and in engine oils. We can supply you with the following chemical products: Dodecenyl succinic anhydride (n-DDSA) (refined) Octenyl succinic ... Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH's in the range of 7.5-8.5) in the 1960's by 0. Wurzburg and E. Mazzerella of the National Starch and Chemical Company [1]. The sodium salt of ASA can be complexed with alum in a similar manner to resin acids to size ...CELLULOSE STRUCTURE HYDROPHOBIZATION BY ALKENYL SUCCINIC ANHYDRIDE (ASA) – A Novel Approach to Performance Explanation a presentationby S. Porkert, Munich University of Applied Sciences S ...@article{Sato2016SurfaceMO, title={Surface modification of cellulose nanofibers with alkenyl succinic anhydride for high-density polyethylene reinforcement}, author={Akihiro Sato and Daisuke Kabusaki and Hiroaki Okumura and Takeshi Nakatani and Fumiaki Nakatsubo and Hiroyuki Yano}, journal={Composites Part A-applied Science and …

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The alkenyl succinic anhydride and derivatives thereof are useful as additives for fuels, lubricating oil compositions, curing agents for epoxy resins, plasticizers, surfactants etc. Alkenyl succinic anhydrides wherein the alkenyl substituent has from about 6 to 18 carbon atoms are of value as a raw material for the production of C 6-C 18 alkyl ...Cashew gum (CG) shows promise of being useful as an agro-based raw material for the production of eco-friendly and biodegradable polymers. In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted ...The reaction between acetic anhydride and water is written as follows: (CH3CO)2O + H2O – 2CH3COOH. This reaction produces two molecules of etanoic acid, a compound that appears as ...The amphiphilicity of octenyl succinic anhydride (OSA)-modified starch is improved due to the introduction of dual functional hydrophilic and hydrophobic groups . Based on its amphiphilicity, OSA-starch is used as an emulsifier and stabilizer in many food or oil-in-water systems, cosmetics, and pharmaceutical products [ 19 – 22 ].Alkenyl Succinic Anhydride (ASA) is sizing agent that is applied as an aqueous emulsion during the papermaking process to improve paper’s hydrophobicity. However, its application becomes difficult as the emulsion quickly destabilizes due to the coalescence phenomenon and the high reactivity of ASA with water. In this work, we …Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield, and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors.Abstract Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsication of ASA using cati-onic starch is conventionally practiced because of the low shelf life of ASA emulsion. We synthesized Janus particles by surfactant-free seeded polymerization to stabilize ASA emulsion.The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the ...Sizing performance of alkenyl succinic anhydride (ASA) emulsion stabilized by polyvinylamine macromolecules. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2018, 539, 132-139. DOI: 10.1016/j.colsurfa.2017.12.014. Qi Zhao, Wenxia Liu, Guodong Li, Lucian A. Lucia, Huili Wang, Dehai Yu.Alkenyl succinic anhydride (ASA) is one of the typical neutral sizes as well as alkyl ketene dimer (AKD) for paper, giving water-repellency to paper efficiently by being added as cationic emulsions to pulp suspension even at 7-9 of pH due to the presence of calcium carbon-ate used as a filler.Mar 1, 2011 ... Abstract Reactive paper sizing agents, such as alkenyl succinic anhydride (ASA), provide hydrophobicity to paper. The reactive anhydride ...Alkenyl Succinic Anhydride (ASA) is sizing agent that is applied as an aqueous emulsion during the papermaking process to improve paper’s hydrophobicity. However, its application becomes difficult as the emulsion quickly destabilizes due to the coalescence phenomenon and the high reactivity of ASA with water. In this work, we …

Alkenyl succinic anhydride (ASA) is a widely used paper sizing agent that is applied in the form of oil-in-water (o/w) emulsions in order to impart a water-resistant character to the resulting paper.Alkenyl succinic anhydrides (ASA) were prepared by an-ene reaction of n-alkyl (C1 to C5) oleates with maleic anhydride. The purified compounds were characterized by FTIR, 1H NMR, and MS analytical methods to elucidate their structures. Their physicochemical properties were systematically studied and found to depend on the length of the alkyl radical. Structure-property relations were ...The optimal reaction conditions for obtaining the maximal yield (around 95%) of alkenyl succinic anhydride from methyl oleate were 235C, a molar ratio of 1.5, and a reaction lasting 8 h. However ...Instagram:https://instagram. arbol genealogico de mi familia Abstract Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsication of ASA using cati-onic starch is conventionally practiced because of the low shelf life of ASA emulsion. We synthesized Janus particles by surfactant-free seeded polymerization to stabilize ASA emulsion. mcmenamins olympic club Usually, when you get a refund from the IRS, you overpaid on your taxes throughout the year. However, you can still receive more money back than you paid to the IRS in the form of ...The URL has moved here ulta besuty DOI: 10.1016/j.carbpol.2021.118126 Corpus ID: 235231465; Alkenyl succinic anhydride modified tree-gum kondagogu: A bio-based material with potential for food packaging. @article{Venkateshaiah2021AlkenylSA, title={Alkenyl succinic anhydride modified tree-gum kondagogu: A bio-based material with potential for food packaging.}, author={Abhilash Venkateshaiah and Karel Havl{\'i}{\vc}ek and Renee L ... open .dat file CELLULOSE STRUCTURE HYDROPHOBIZATION BY ALKENYL SUCCINIC ANHYDRIDE (ASA) – A Novel Approach to Performance Explanation a presentationby S. Porkert, Munich University of Applied Sciences S ... kansas city mo to chicago il 2 1. INTRODUCTION Alkenyl succinic anhydrides (ASAs) are used as sizing agents in the paper industry and also find use in the drilling of oil wells and as fuel additives.1,2 ASAs are formed by an Alder-ene reaction of a linear alkyl olefin and maleic anhydride.3 It is widely known that isomerised olefins give ASAs with lower freezing temperatures – ASA from C … how can i unsend an email @article{Sato2016SurfaceMO, title={Surface modification of cellulose nanofibers with alkenyl succinic anhydride for high-density polyethylene reinforcement}, author={Akihiro Sato and Daisuke Kabusaki and Hiroaki Okumura and Takeshi Nakatani and Fumiaki Nakatsubo and Hiroyuki Yano}, journal={Composites Part A-applied Science and …DOI: 10.1016/j.ces.2020.116407 Corpus ID: 233528964; Stabilization of the emulsion of Alkenyl Succinic Anhydride (ASA) in water using cellulose nanofibrils @article{Arancibia2021StabilizationOT, title={Stabilization of the emulsion of Alkenyl Succinic Anhydride (ASA) in water using cellulose nanofibrils}, author={Fernando Arancibia and Eduardo Izquierdo and Miguel Pereira}, journal={Chemical ... airfare from buffalo to new york city CELLULOSE STRUCTURE HYDROPHOBIZATION BY ALKENYL SUCCINIC ANHYDRIDE (ASA) – A Novel Approach to Performance Explanation a presentationby S. Porkert, Munich University of Applied Sciences S ...Alkenyl succinic anhydride (ASA) is an internal sizing chemical, normally applied in paper and board making at roughly neutral pH. For the paper and paperboards which have huge proportion of secondary fibers and mechanical cellulosic pulp, ASA has the advantage in sizing.Synthesis of alkenyl succinic anhydrides from methyl esters of high oleic sunflower oil. Laboratoire de Chimie. Alkenyl succinic anhydrides (ASA) have been prepared by ene … kill dolls Alkenyl succinic anhydrides (ASA) have been prepared by ene‐reaction of high‐oleic sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. Response surface methodology (RSM) was used to investigate the influence of two factors: reaction temperature and molar ratio between maleic anhydride (MA) and methyl esters (SME). … fly tickets to paris Abstract Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsication of ASA using cati-onic starch is conventionally practiced because of the low shelf life of ASA emulsion. We synthesized Janus particles by surfactant-free seeded polymerization to stabilize ASA emulsion. unblocked games roblox Succinic Anhydride. 113 Alkenyl succinic anhydrides (extensively used in the papermaking industry as paper sizing agents when manufactured by reaction of maleic anhydride with C14–C22 i-olefins) have been prepared by the ene reaction of the methyl esters of high-oleic sunflower oil with maleic anhydride in a 50% xylene medium. checkers 2 player Here, an easy-fabricating, stable, and high-performance alkenyl succinic anhydride (ASA) paper-sizing emulsion is developed, which is stabilized by lauric arginate (LAE)/cellulose nanocrystal (CNC ...Surface treatment of nanocellulose (e.g., silane agent, alkenyl succinic anhydride) is an applicable method to moderate nanofiber agglomeration and improve interfacial adhesion [93,94, 98]. In ...Sep 1, 2005 · Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH's in the...